Process for creating structured porosity in thermal barrier...

Coating processes – Nonuniform coating – Applying superposed diverse coatings or coating a coated base

Reexamination Certificate

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C427S282000, C427S272000, C427S456000, C427S448000, C427S596000, C427S250000, C427S252000, C427S255320, C427S255700

Reexamination Certificate

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06528118

ABSTRACT:

FIELD OF THE INVENTION
This invention relates generally to gas turbine engines, and in particular. to a cooled flow path surface region.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application references co-pending applications assigned to the assignee of the present invention, which are identified as Ser. No. 09/707,023 entitled “Directly Cooled Thermal Barrier Coating System”, Ser. No. 09/707,027 entitled “Transpiration Cooling in Thermal Barrier Coating” and Ser. No. 09/707,024 entitled “Multi-layer Thermal Barrier Coating with Integrated Cooling System,” the contents of which are incorporated herein by reference.
BACKGROUND OF THE INVENTION
In gas turbine engines, for example, aircraft engines, air is drawn into the front of the engine, compressed by a shaft-mounted rotary-type compressor, and mixed with fuel. The mixture is burned, and the hot exhaust gases are passed through a turbine mounted on a shaft. The flow of gas turns the turbine, which turns the shaft and drives the compressor and fan. The hot exhaust gases flow from the back of the engine, driving it and the aircraft forward.
During operation of gas turbine engines, the temperatures of combustion gases may exceed 3,000° F., considerably higher than the melting temperatures of the metal parts of the engine, which are in contact with these gases. Operation of these engines at gas temperatures that are above the metal part melting temperatures is a well established art, and depends in part on supplying cooling air to the metal parts through various methods. The metal parts of these engines that are particularly subject to high temperatures, and thus require particular attention with respect to cooling, are the metal parts forming combustors and parts located aft of the combustor including turbine blades and vanes and exhaust nozzles.
The hotter the turbine inlet gases, the more efficient is the operation of the jet engine. There is thus an incentive to raise the turbine inlet gas temperature. However, the maximum temperature of the turbine inlet gases is normally limited by the materials used to fabricate the components downstream of the combustors such as the vanes and the blades of the turbine. In current engines, the turbine vanes and blades are made of nickel-based superalloys, and can operate at temperatures of around 2100° F.
The metal temperatures can be maintained below melting levels with current cooling techniques by using a combination of improved cooling designs and thermal barrier coatings (TBCs). For example, with regard to the metal blades and vanes employed in aircraft engines, some cooling is achieved through convection by providing passages for flow of cooling air from the compressor internally within the blades so that heat may be removed from the metal structure of the blade by the cooling air. Such blades have intricate serpentine passageways within the structural metal forming the cooling circuits of the blade.
Small internal orifices have also been devised to direct this circulating cooling air directly against certain inner surfaces of the airfoil to obtain cooling of the inner surface by impingement of the cooling air against the surface, a process known as impingement cooling. In addition, an array of small holes extending from a hollow core through the blade shell can provide for bleeding cooling air through the blade shell to the outer surface where a film of such air can protect the blade from direct contact with the hot gases passing through the engine, a process known as film cooling.
In another approach, a thermal barrier coating (TBC) is applied to the turbine blade component, which forms an interface between the metallic component and the hot gases of combustion. The TBC includes a ceramic coating that is applied to the external surface of metal parts to impede the transfer of heat from hot combustion gases to the metal parts, thus insulating the component from the hot combustion gas. This permits the combustion gas to be hotter than would otherwise be possible with the particular material and fabrication process of the component.
TBCs include well-known ceramic materials, for example, yttrium-stabilized zirconia (YSZ). Ceramic TBCs usually do not adhere well directly to the superalloys used as substrate materials. Therefore, an additional metallic layer called a bond coat is placed between the substrate and the TBC. The bond coat may be made of a nickel-containing overlay alloy, such as a MCrAlY, where M is an element selected from the group consisting of Ni, Co, Fe and combinations thereof, or other compositions more resistant to environmental damage than the substrate. Alternatively, the bond coat may be a diffusion nickel aluminide or platinum aluminide, which is grown into the surface of the substrate and whose surface oxidizes to form a protective aluminum oxide scale that provides improved adherence of the ceramic top coatings. The bond coat and overlying TBC are frequently referred to as a thermal barrier coating system.
In an effort to improve TBC life, U.S. Pat. No. 5,419,971 to Skelly et al., assigned to the assignee of the present invention, is directed to small grooves placed in the bond coat layer and/or an interfacial layer lying between the substrate and the TBC to minimize spallation resulting from propagation of cracks formed in TBC systems. The grooves are formed by an ablation process using an ultraviolet laser such as an excimer laser. These grooves have been demonstrated to improve TBC life by facilitating the formation of desired TBC microstructure, which arrests the propagation of cracks formed within TBC, thereby reducing the incidence of spallation, defined as the chipping or flaking away of the coating.
Attempts to improve the life of the bond coat include U.S. Pat. No. 5,034,284 to Bornstein et al. which discloses a porous strain isolation layer placed between the substrate and the bond coat. The porous layer is formed by spraying a mixture of alloy and polymer particles with subsequently heating to eliminate the polymer. The pores are in a random pattern and do not create channels.
The three co-pending applications referenced above disclose small cooling or micro channels within or near the bond coat to improve bond coat and/or TBC system life. These micro channels may communicate directly with at least one cooling circuit contained within the component from which they receive cooling air, thereby providing direct and efficient cooling for the TBC system. To form these micro channels, a surface is masked with a masking material, the masking material forming a pattern on the surface overlying at least one cooling fluid supply contained within the component. The masking material is subsequently removed, leaving hollow micro channels to actively cool the flow path surface region, thus achieving a better, more efficient engine performance.
Creating micro grooves with an excimer laser is a slow and expensive process. Utilizing a masking material which must later be removed also adds additional time and expense. Thus, there is an ongoing need for improved methods for economically creating micro grooves or channels used to encourage favorable microstructure formation and/or improve the environmental resistance and long-term stability of the thermal barrier coating system, so that higher engine efficiencies can be obtained. The present invention fulfills this need, and further provides related advantages.
SUMMARY OF THE INVENTION
The present invention provides an improved method for creating micro grooves or channels within or adjacent to the TBC layer applied to a gas turbine engine component, for example, a blade or vane.
In one embodiment, a substrate surface is first coated with a bond coat, for example, an approximately 0.002″ thick diffusion PtAl or an overlay NiAl based alloy coating. A wire mesh is placed a predetermined distance above the bond coat surface, and an inner TBC layer, approximately 0.002″ thick is then deposited on top of the bond coat. The wires in the mesh shadow the TBC deposition, forming structured grooves on the TBC su

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