Stock material or miscellaneous articles – Hollow or container type article – Polymer or resin containing
Reexamination Certificate
2000-10-12
2003-07-22
Pyon, Harold (Department: 1772)
Stock material or miscellaneous articles
Hollow or container type article
Polymer or resin containing
C428S036910, C428S035700, C264S331140, C264S332000
Reexamination Certificate
active
06596357
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to fusing members for use in photocopying and other printing operations which have a non-stick coating on a compliant baselayer, and more particularly to a multi-layer roll having a fluoropolymer coating bonded to a compliant silicone rubber layer on a metallic core.
BACKGROUND OF THE INVENTION
The use of a fusing member constructed with a non-stick material as a top layer and a heat resistant base layer has been known in the reprophotographic art. Typical non-stick materials which have been used include polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), perfluoroalkoxy (PFA), polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene (ECTFE), ethylene-tetrafluoroethylene (ETFE), polyvinylidene fluoride (PVDF) and polyvinyl fluoride (PVF), silicone compounds and blends of these materials.
Fluoropolymer resin by itself, though an excellent non-stick material, provides no compliance. Silicone compounds on the other hand, while compliant are readily adversely affected by silicone oil which is commonly used as a release agent in fusing applications. As the silicone compound swells, the nip characteristics change, affecting the fuse quality of the images. The silicone coating becomes susceptible to mechanical damage, such as abrasion by the print media, picker fingers and hardened toner that accumulates in the system. Fluoroelastomers, on the other hand are tougher materials which are more resistant to silicone oil. However, fluoroelastomers generally require a special oil to function in a fuser application. These special silicone oils are costly and when present on the copy media make writing on the media noticeably more difficult.
It is preferable to have a material combining the non-stick properties of fluoropolymer resins and the compliant properties of silicone elastomers. U.S. Pat. No. 3,435,500 to Aser and U.S. Pat. No. 4,789,565 to Kon disclose applying a polytetrafluoroethylene resin to a silicone rubber surface which is adhered to a metal insert and sintering the resin. Another U.S. Pat. No. 5,547,759, to Chen, et al. discloses a method of bonding a fluoropolymer resin to various substrates including silicone, via a layer of fluoroelastomer and fluoropolymer containing a polyamide-imide layer. The fluoropolymer in the latter case assumes the role of an insulator to prevent degradation of the compliant substrate and the adhesion between the layers during the sintering process.
Since most commercially available materials today compromise one necessary property in some way or another, the various solutions suggested in the prior art are not fully satisfactory. This is particularly true in color systems where gloss and gloss maintenance is a key element of the fusing system. Here, a fluoropolymer coating possessing easy wettability by a silicone release agent is a highly desirable surface characteristic.
Accordingly, it remains highly desirable to provide a fuser member where the top layer provides maximum release properties and is not affected by the use of release agents commonly in use as well as possessing compliant properties.
SUMMARY OF INVENTION
Generally speaking, in accordance with the invention, a multilayer fuser roll construction having a compliant silicone baselayer bonded to a metallic core and a fluoropolymer coating bonded to the silicone layer is provided. This multilayer roll includes a primer layer of a blend of silicone and polyamide resin on the silicone baselayer which is pre-baked in an IR oven prior to disposing a PTFE primer thereon for bonding the fluorocarbon resin coating thereon.
Accordingly, it is an object of the invention to provide an improved multi-layer fuser roll having a non-stick coating on a compliant base layer adhered to a metallic core.
It is a further object of the invention to provide a multi-layer fuser roll having a fluoropolymer coating on a compliant base layer adhered to a metallic core.
It is another object of the invention to provide a multi-layer fuser roll having a fluoropolymer coating on a silicone rubber base coat adhered to a metallic core.
It is yet another object of the present invention to provide a novel primer composition for bonding a fluoropolymer coating to a compliant base layer adhered to a metallic core.
It is yet a further object of the invention to provide a method of fabricating a multi-layer fuser roll having a non-stick coating and a compliant base layer on a metallic core.
Still other objects and advantages of the invention will in part be obvious and will in part be apparent from the specification and drawings.
The invention accordingly comprises the several steps and the relation of one or more of such steps with respect to each of the others, and the composition possessing the features, properties and the relation of constituents and the article possessing the features, properties, and the relation of elements, which are all exemplified in the following detailed disclosure, and the scope of the invention will be indicated in the claims.
REFERENCES:
patent: 3435500 (1969-04-01), Aser
patent: 4087394 (1978-05-01), Concannon
patent: 4139576 (1979-02-01), Yoshimura et al.
patent: 4789565 (1988-12-01), Kon et al.
patent: 5011401 (1991-04-01), Sakurai et al.
patent: 5035950 (1991-07-01), DelRosario
patent: 5153660 (1992-10-01), Goto
patent: 5253027 (1993-10-01), Goto
patent: 5474850 (1995-12-01), DelRosario et al.
patent: 5547759 (1996-08-01), Chen et al.
patent: 5709949 (1998-01-01), Chen et al.
patent: 5998034 (1999-12-01), Marvil et al.
patent: 0 321 162 (1989-06-01), None
patent: 0321162 (1989-06-01), None
patent: 0 531 011 (1993-03-01), None
patent: 0531011 (1993-03-01), None
patent: 0 763 568 (1997-03-01), None
patent: 763568 (1997-03-01), None
patent: 2509544 (1996-06-01), None
Derwent Abstract: XP002101524 & JP 56 090862 A (Daikin Kogyo KK). Jul. 23, 1981.
DelRosario Chris F.
Marvil Timothy D.
Moss Stace
Navarra John
Raabe, Jr. Orville R.
Ames Rubber Corporation
Patterson Marc
Pyon Harold
Reed Smith LLP
Wolfson Michael I.
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