Process for producing high quality natural rubber

Details Process for producing high quality natural rubber Process for producing high quality natural rubber

2000-12-29

2002-12-10

Wu, David W. (Department: 1713)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Processes of preparing a desired or intentional composition...

C525S054450, C525S192000, C525S197000, C525S054400, C524S528000

Reexamination Certificate

active

06492447

ABSTRACT:

BACKGROUND OF THE INVENTION
Natural rubber is produced by a wide variety of plant species. For instance, Guayule rubber is produced by
Parthenium argentatum
which is a shrub found in Mexico and the southwestern part of the United States. However, natural rubber is cultivated on a commercial basis almost exclusively from
Hevea brasiliensis
which is a tree that is indigenous to Brazil.
Hevea brasiliensis
trees grow only within the tropics and subtropics where frost is never encountered and where heavy annual rainfalls occur. In fact,
Hevea brasiliensis
trees are typically cultivated only within a latitude of 15° of the equator.
Today, most natural rubber comes from rubber plantations where
Hevea brasiliensis
trees (rubber trees) are cultivated. The rubber is present in latex which is an emulsion or dispersion of rubber in water produced by the trees. The rubber latex occurs in the bark of the rubber trees in tubes or ducts which spiral from left to right as they ascend the trees. The latex is tapped from the rubber trees about every other day. This is done by making a spiral cut downward from left to right at an angle of about 30° for half of the circumference of the tree. The cut is made almost, but not completely, through the bark. In any case, the cut is deep enough to pierce the latex tubes or ducts which allows the latex to flow through the cut to a spout that is inserted at the lowest part of the cut. The spout is situated in a manner that directs the flow of latex into a collection cup.
Each tapping yields about a cup of latex that contains approximately 30 percent (about 50 grams) of natural rubber. Each subsequent cut in the tapping process in made immediately below the preceding cut. It is a common practice to rest the rubber trees after periods of heavy tapping.
Some of the latex collected by the tapping process is concentrated to a solids content of about 60 percent and sold as natural rubber latex. Such natural rubber latex is used in manufacturing dipped goods, such as rubber gloves and prophylactics. However, most of the latex collected is coagulated into dry rubber. This is typically done by straining the latex through a sieve to remove particles of bark and dirt and then diluting the latex with clean water to a solids content of about 15 percent. Then, the diluted latex is coagulated by the addition of formic acid or acetic acid. The rubber crumbs generated by the coagulation are then washed, dried and compacted into blocks for shipping. Such natural rubber made by the coagulation of latex is of high quality and is typically classified as SIR3 CV-60 (maximum dirt content of 0.03 percent and constant Mooney viscosity of 60).
In actual practice, about 20 percent of the latex tapped from rubber trees coagulates in the collection cups. This is known as cup-lump rubber because it naturally coagulates and forms a lump in the collection cup. Cup-lump rubber is also sometimes referred to as “tree lace” because it can also coagulate into strips which can be removed from the cuts in the tree's bark. A small amount of preservative, such as sodium sulfite, is frequently added to the collection cup to inhibit coagulation. However, the use of such preservatives does not eliminate the generation of cup-lump rubber. Since cup-lump rubber has an unknown viscosity and inherently contains a high level of impurities, such as bark, leaves, insects, silt, sand, dirt and other contaminates, it is of much lower commercial value. Cup-lump rubber is typically classified as SIR20 VK (maximum dirt content of 0.20 percent and unknown viscosity).
In some cases, cup-lump rubber is blended with high quality SIR3 CV-60 rubber to make a rubber blend of an intermediate grade. For instance, cup-lump rubber is commonly blended with SIR3 CV-60 rubber to make a blend designated as SIR5 CV-60 which has a maximum dirt content of 0.05 percent and a constant viscosity of 60. However, it has heretofore not been possible to make high quality SIR3 CV-60 rubber with blends containing significant quantities of cup-lump rubber.
SUMMARY OF THE INVENTION
This invention relates to a technique for making a high quality natural rubber composition having a dirt content of less than 0.03 percent and a constant Mooney viscosity of 60 by blending cup-lump rubber with natural rubber made by coagulating natural rubber latex. The high quality natural rubber composition of this invention can be made with up to 60 percent cup-lump rubber.
This invention more specifically discloses a process for producing a high quality natural rubber composition from a feed stream that is comprised of natural rubber latex and cup-lump rubber which comprises:
(1) removing foreign material from the cup-lump rubber to produce cleaned cup-lump rubber;
(2) reducing the particle size of the cleaned cup-lump rubber to an average particle size of less than 35 millimeters;
(3) coagulating the natural rubber latex to produce latex rubber coagulum;
(4) mixing the cleaned cup-lump rubber with the latex rubber coagulum to produce a blend of cup-lump rubber and latex rubber coagulum, wherein a maximum of 60 percent by weight of the cup-lump rubber is mixed into the blend;
(5) reducing the particle size of the blend of cup-lump rubber and latex rubber coagulum to a maximum particle size of 3 millimeters to produce a small particle size rubber blend;
(6) conveying the small particle size rubber blend in an air medium through a pneumatic transfer system;
(7) mixing about 0.1 weight percent to about 0.2 weight percent of an antioxidant into the small particle size rubber blend as its being conveyed in the air medium through the pneumatic transfer system;
(8) transferring the small particle size rubber blend in the air medium into a gas-cyclone; and
(9) separating the air from the small particle size rubber blend to produce the high quality natural rubber composition.
DETAILED DESCRIPTION OF THE INVENTION
The cup-lump rubber used in the process of this invention is collected on the plantation in the normal way. After being collected, the cup-lump rubber is then cleaned to remove foreign matter, such as dirt, sand, bark, leaves, insects, silt and other contaminants. This can be accomplished by washing the cup-lump rubber with clean water. For instance, the clean water can be sprayed onto the cup-lump rubber or the cup-lump rubber can be emersed into a vessel containing water. The cup-lump rubber can also be separated from dirt and other impurities by use of a hydrocyclone. After being washed, the cup-lump rubber will normally be dried.
The cleaned cup-lump rubber will then be reduced in particle size to an average particle size of less than 35 millimeters. This can be accomplished by mechanically grinding the cleaned cup-lump rubber. Any equipment that is capable of reducing the particle size of the cleaned cup-lump rubber to an average particle size of less than 35 millimeters can be used.
Natural rubber latex is coagulated into latex rubber coagulum and subsequently used in making the high quality natural rubber compositions of this invention. The natural rubber latex collected from rubber trees typically has a solids content of about 30 percent. The latex is normally filtered through a sieve or screen to remove large contaminants, such as bark, leaves and insects, and is then diluted with clean water to a solids content which is the range of about 10 to about 25 percent. The natural rubber latex is preferably diluted to a solids content which is within the range of about 12 percent to about 18 percent.
After optionally being diluted, the natural rubber latex is coagulated by the addition of formic acid and/or acetic acid. This results in solid natural rubber particles separating from the aqueous phase. The latex rubber coagulum (solid natural rubber particles) can then be recovered from the aqueous phase, optionally, washed in clean water, and then dried.
The cleaned cup-lump rubber is then mixed with the latex rubber coagulum to make a blend of cup-lump rubber and latex rubber coagulum. A maximum of 60 weight percent cup-lump rubber should

Affiliated with

Also associated with

Rating

Process for producing high quality natural rubber does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for producing high quality natural rubber, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for producing high quality natural rubber will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2964849