Method for Kalina combined cycle power plant with district...

Power plants – Motive fluid energized by externally applied heat – Process of power production or system operation

Reexamination Certificate

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Details

C060S651000, C060S653000, C060S671000, C060S039010, C060S039182

Reexamination Certificate

active

06347520

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to a method and apparatus for improving the efficiency of a combined cycle power plant using excess thermal energy from the gas turbine exhaust of a power plant to supply hot water (“district water”) to a hot water system or network in a more thermally efficient manner. In particular, the invention relates to a new method for converting excess thermal energy into electric power by integrating a modified Kalina-type thermodynamic cycle into a district heating and cooling system in an efficient and cost-effective manner. The principal benefit of the new method is the recovery of additional heat for use with district water, which in turn can be used to heat homes and buildings by conventional means (e.g., radiators or other standard heat transfer devices). The invention also relates to the use of a thermal energy source from a gas turbine exhaust in a more efficient manner during the summer months (when demand for district water heating is low) by incorporating an intermediate pressure turbine into the process in an alternative embodiment in accordance with invention.
In the past, district heating and cooling systems have been integrated into power plants to take advantage of excess thermal energy sources. However, virtually all such systems have been integrated into plants that rely on traditional Rankine bottoming cycles. A conventional Rankine cycle has a relatively low thermal efficiency. Thus, the use of additional Rankine cycles to recover waste heat, particularly in bottoming cycles, normally is not cost-justified because of the efficiency losses inherent in such designs.
The Kalina thermodynamic cycle has previously been utilized to increase the thermodynamic efficiency of natural gas turbine combined cycle applications such as the process described in U.S. Pat. No. 5,440,882 (known generally as a “Kalina 6” cycle). The working fluid in a Kalina 6 cycle consists of a multi-component mixture that normally has only one low boiling point component and one high boiling point component. The preferred form of the working fluid is ammonia and water (NH
3
/H
2
), although other high and lower boiling point mixtures of different components are theoretically possible. The mixture increases the thermodynamic efficiency of the system by virtue of the non-isothermal vaporization and condensation characteristics of the multi-component fluid which allow for heat absorption and rejection but with significantly lower irreversibility. This known characteristic of Kalina cycles allows the mixture to recover heat at lower temperatures than pure water in Rankine cycles. A regenerative boiler is typically used in a Kalina cycle in order to increase the overall efficiency of the system by vaporizing part of the working fluid using the superheated vapor of the high pressure (“HP”) turbine outlet, thereby increasing the vapor production in a heat recovery vapor generator (“HRVG”).
A conventional Kalina cycle has not heretofore been utilized in direct combination with district water heating and cooling systems, particularly as defined by the present invention using a direct, single stage condenser, in general, Kalina cycles include complex distillation condensation subsystems (“DCSS”) and are more expensive to construct and operate as compared to a Rankine cycles because they require additional process equipment and more costly materials of construction for NH
3
/H
2
O applications.
The design in accordance with the present invention shares a common element with the conventional Kalina cycle, namely, the regenerative boiler. Nevertheless, a need remains in the art for a method to increase the thermal efficiency of the traditional Rankine cycle district water heating and cooling systems by taking advantage of the potential increases in thermal efficiency of a Kalina bottoming cycle to heat and cool district water. A need also exists to decrease the number of processing units (and overall installation and operating costs) associated with the use of a conventional Kalina cycle to perform such tasks.
The present invention achieves those objectives by integrating a thermally efficient Kalina-type bottoming cycle with district water heating and cooling loads in the manner described below. The invention also includes a regenerative economizer that functions in combination with the regenerative boiler for achieving additional thermodynamic gains.
BRIEF DESCRIPTION OF THE INVENTION
The preferred method for implementing a simplified Kalina thermodynamic cycle with a district water heating and cooling plan in accordance with the invention includes the following basic process steps:
(1) vaporizing a working fluid by transferring thermal energy from a gas turbine (“GT”) exhaust to the working fluid in the HRVG;
(2) expanding the working fluid through the HP turbine to produce electric energy, as well as a shell-side heat source;
(3) transferring thermal energy from the HP turbine outlet to the working fluid through a regenerative economizer and a regenerative boiler to produce a superheated, pressurized vapor working fluid and spent exhaust stream; and
(4) condensing the working fluid by transferring thermal energy to the district water.
An alternative embodiment of the invention includes steps (1) and (2), but modifies the step of expanding the vaporized working fluid by passing the expanded fluid leaving the HP turbine through a second intermediate pressure (“IP”) turbine to produce additional power, condensing the working fluid through a condenser and recombining the condensed working fluid with the condensate from the district water unit.
In order to carry out the above method steps, the present invention also includes an apparatus for improving the thermal efficiency of a combined cycle plant that includes the following basic components:
a. a heat recovery vapor generator (HRVG) for vaporizing, superheating, and pressurizing a working fluid;
b. a high pressure turbine for expanding the working fluid to generate electric power;
c. an intermediate pressure turbine for expanding the working fluid to produce power;
d. a first heat exchanger for cooling the multi-component working fluid exhaust leaving the high pressure turbine, while vaporizing recycled working fluid, preferably with the high pressure exhaust stream on the shell side and the recycled fluid on the tube side; and
e. a second heat exchanger downstream and in series with the first exchanger for further cooling the multi-component working fluid exhaust and heating the recycled working fluid, preferably with the vapor exhaust on the shell side and the recycled on the tube side;
f. a condenser in series with the first and second heat exchangers for condensing the cooled working fluid on one side and heating district water on the side.
In the preferred treatment method, the working fluid is pressurized, vaporized and superheated in the HRVG. The low boiling temperature component in the working fluid is combined with the high boiling temperature component to allow the mixture to capture thermal energy at a lower temperature and, in effect, store more energy. The working fluid is then expanded through the HP turbine to produce electric power in a conventional manner. The exhaust from the HP turbine then serves as a heat source for the regenerative economizer and the regenerative boiler. Thus, in the preferred embodiment, virtually all of the sensible heat from the HP turbine outlet is transferred either to the district water in the condenser or to the working fluid in the regenerative economizer and regenerative boiler.
In another aspect of the invention, the HP turbine outlet stream can be used as the working fluid for the IP turbine to create additional electric power. Integrating the district water heating system with a modified Kalina cycle in accordance with the invention results in the Kalina cycle being simplified in form, thereby reducing unit construction and operating costs. As noted above, a conventional Kalina cycle has power generation as the primary objective and thus does not inc

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