Vapor control

Fluent material handling – with receiver or receiver coacting mea – Diverse fluid containing pressure filling systems involving... – Filling with exhausting the receiver

Reexamination Certificate

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Details

C141S083000, C141S289000

Reexamination Certificate

active

06394149

ABSTRACT:

BACKGROUND OF THE INVENTION
When many organic chemical liquid compositions, such as hydrocarbon fuels or similar materials, are loaded from a loading facility or system into the tanks or holds of shipping vessels, significant quantities of volatile organic compounds may be released. The vapor released may not only be environmentally polluting but, in sufficient amounts, may present a dangerous fire or explosion hazard. To overcome these concerns, elaborate vapor control schemes and systems have been incorporated over the years into loading operations and systems for capturing the vapor released during loading.
In many instances, the vapor control systems were designed or sized to handle volumes of released vapor based on expected volumes of the fuels, etc., to be loaded, the expected volumes being, in turn, based on best estimates of future demand. However, a combination of unexpected increased consumer demand and increasingly stringent governmental environmental regulations are causing many existing vapor control systems to run near capacity.
With demand for these materials expected to increase to even greater levels, it is evident that existing vapor control systems will be unable to process the volumes of volatile component(s) at a regulatorily required level. While new systems may be installed, or existing vapor control systems may be expanded, significant capital costs are involved. In addition, until the new or expanded systems are operational, loading operations will be restricted by the limited capacity of the current systems. Accordingly, there has been a need for an approach for handling increased loading volumes which avoids the costs and limitations mentioned. The invention addresses this need, and, in a preferred aspect, is directed to loading operations, apparatus, and systems for loading organic chemical liquids, particularly various grades of gasoline, diesel and other distillates, and compositions referred to generally as petroleum hydrocarbons.
SUMMARY OF THE INVENTION
The invention proceeds from an evaluation of the operations of the loading terminal or system, including the spectrum of liquid compositions to be loaded, and from the discovery that circumstances may allow, during loading of some liquid compositions in a vessel, non-use or bypass of the vapor control system or unit. More particularly, some organic chemical liquids to be loaded are of such limited volatility that release or venting of the very minor quantities of vapors released from the vessel during loading will be minimally or essentially non-polluting and the loading operation will therefore remain in compliance with governmental environmental regulations. As employed herein, the expression “liquid of limited volatility” refers to an organic chemical liquid, including mixtures thereof, having such limited vapor pressure that its handling in the environment, such as in a loading operation, does not generate a quantity of vapor or vapors sufficient to exceed governmental environmental regulations or standards. In normal loading operations, such as at a refinery or chemical plant, the vapor pressure of an organic chemical liquid to be loaded will either be known, or may be determined by routine testing, so that a comparison of the particular liquid's true vapor pressure at standard conditions with published governmental environmental limits, which may vary from time to time, may readily be made and the liquid's suitability for venting of vapor determined. At the present time, an organic chemical liquid having a true vapor of below 1.5 psia at 60° F. would meet such governmental requirements.
Broadly, therefore, the invention relates to a novel procedure, apparatus, and system for loading organic chemical liquids in a transporting vessel. In addition, a vapor control logic system is provided which controls flow direction of vapor captured from a transporting vessel being loaded, either to a vapor control system or to vent in response to user input or inputs. Accordingly, in one aspect of the invention, there is input into an input or input means of the logic system mentioned the nature of the organic chemical liquid to be loaded and, if the liquid is a liquid of limited volatility, a further user determination input of whether or not the previous load in the vessel was a liquid of limited volatility. A processor, coupled to said user input or inputs, and responsive thereto, being configured to process one or both of said input determinations, outputs directions for control or disposition of vapor captured or collected while loading the vessel, as described more fully hereinafter.
Alternatively, the vapor control logic system may be designed to input first the user determination of whether or not the previous load in the vessel was a liquid of limited volatility, and, if the previous load was a liquid of limited volatility, a user determination input of the nature of the organic chemical liquid to be loaded in the vessel. In a similar manner, the processor, coupled to said user input or inputs and responsive thereto, and appropriately configured to process one or both of said input determinations, outputs directions for control of vapor captured, as also described more fully hereinafter.
In both cases, the processor, which will be a computer, will be programmed or configured to output directions, as follows. If a load to be loaded is a volatile organic chemical liquid, or if the previous load of the vessel was not a liquid of limited volatility, the flow of captured vapor will be directed to the vapor control system or unit. If the load to be loaded is a liquid of limited volatility, but the previous load was not, the captured vapor will be sent to the vapor control system. However, if the load to be loaded is a liquid of limited volatility, and the previous load of the vehicle was a liquid of limited volatility, the flow of captured vapor(s) will be diverted from the vapor control system and directed to means for venting to atmosphere. If it is not known or ascertainable if the previous load of the vehicle was a liquid of limited volatility, the flow of captured vapors is directed to the vapor control unit. As a failsafe in either case mentioned, the system may further provide optional means for analyzing the captured vapors, as described hereinafter, for preventing an inappropriate atmospheric release.
In a preferred embodiment of the invention, there is input into the logic system the nature of the organic chemical liquid to be loaded and, if a distillate, whether or not the load previously carried by the vessel was a distillate composition. As utilized herein, the expressions “distillate” and “distillate composition”, or plural variants thereof, are understood to refer to liquid of limited volatility which is refined from petroleum, and comprising refined hydrocarbon mixtures having a true vapor pressure of below 1.5 psia at 60° F. As will be understood by those skilled in the art, some compounds or components present in such hydrocarbon mixtures are not composed solely of carbon and hydrogen, but may contain other elements, such as nitrogen, oxygen, and sulfur. Common distillates include diesel, oils, such as #1 and #2 fuel oils, kerosene, home heating fuel oil, high sulfur fuel oil, and similar liquids.
In this preferred embodiment, the processor processes the input, and controls the flow of captured or vapor or vapors, as described. If the load to be loaded is not a distillate, e.g., is gasoline, or if the previous load of the vehicle was not a distillate, the flow of captured vapor will be directed to the vapor control unit. If the load to be loaded is a distillate and the previous load of the vehicle was a distillate, the very minimal flow of captured or collected vapor will be diverted from the vapor control system and directed for venting to atmosphere. If it is not known or ascertainable if the previous load of the vehicle was a distillate, the flow of released vapors is directed to the vapor control unit. As already mentioned, as a failsafe, the system may provide

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