Volatile uranyl compounds

Details Volatile uranyl compounds Volatile uranyl compounds

1978-11-16

1981-01-06

Sebastian, Leland A.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

204DIG11, 2604291, 260704, 260706, C07D30712, C07F 500

Patent

active

042435978

ABSTRACT:
Novel compositions of matter are disclosed having the formula UO.sub.2 AA'L.sub.n, wherein n is 0 or 1, and in which A and A' are anions whose conjugate acids have boiling points less than about 200.degree. C. and pK.sub.a values of 4.8 or less, L is a neutral ligand having a boiling point less than about 190.degree. C. and having an equilibrium constant for the exchange reaction with tetrahydrofuran of between about 10.sup.-3 and 10.sup.3, and the combination of A, A' and L satisfy five or six coordination sites of the central uranium atom.

REFERENCES:
Casellato et al., Inorg. Chimica Acta, vol. 18, pp. 84 to 86 (1976).
Subramanian et al., J. Inorg. Nucl. Chem., vol. 33, pp. 3001 to 3009 (1971).

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