Compositions: coating or plastic – Materials or ingredients – Pigment – filler – or aggregate compositions – e.g. – stone,...
Reexamination Certificate
1999-12-16
2002-01-08
Green, Anthony (Department: 1755)
Compositions: coating or plastic
Materials or ingredients
Pigment, filler, or aggregate compositions, e.g., stone,...
C106S402000, C106S408000, C106S410000, C106S415000, C106S436000, C106S447000, C106S448000, C106S456000, C106S460000, C106S471000, C106S472000, C106S476000, C106S493000, C106S494000, C106S495000, C106S496000, C106S497000, C106S498000, C524S533000
Reexamination Certificate
active
06336966
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to pigment dispersions containing pigment, an aqueous carrier, and a pigment dispersant. The pigment dispersant is prepared by controlled radical polymerization, and has star-type architecture in which arm segments extend out from a core segment. Each arm of the pigment dispersant has hydrophobic and hydrophilic polymeric chain segments.
BACKGROUND OF THE INVENTION
Pigmented coating compositions are used in a wide variety of applications including, for example, corrosion resistant primers and decorative topcoats in the automotive, industrial and appliance markets. The preparation of pigmented coating compositions generally involves mixing binder resin(s), crosslinker(s), additives, e.g., flow additives, and solvents with a compatible pigment dispersion. Pigment dispersions are typically prepared by mixing dry pigment with a pigment dispersant in the presence of a carrier medium, e.g., an aqueous carrier medium.
Dry pigments are available commercially in the form of agglomerated pigment particles. Pigment agglomerates are more likely to settle out of pigment dispersions and/or pigmented coating compositions, and are accordingly undesirable. To break the pigment agglomerates down into smaller agglomerates and/or individual particles generally requires the use of energy intensive mixing means (commonly referred to as grinding), e.g., sand mills and ball mills. During the grinding process the pigment agglomerates are broken down into smaller agglomerates and/or individual particles the surfaces of which are wetted by the pigment dispersant. The pigment dispersant suspends or disperses the pigment particles in the carrier medium and prevents their re-agglomeration on storage. It is desirable that the pigment dispersion remain substantially stable, e.g., showing minimal pigment settling and viscosity change with time, prior to its use in the preparation of a pigmented coating composition.
Reducing the environmental impact of pigmented coatings compositions, in particular that associated with emissions into the air of volatile organics during their use, has been an area of ongoing investigation and development in recent years. Accordingly, interest in aqueous pigment dispersions has been increasing due, in part, to the inherently low volatile organic content (VOC) of the aqueous pigmented coatings prepared therefrom, which can significantly reduce air emissions during the application process.
Pigment dispersants used in aqueous pigment dispersions are preferably compatible with both the aqueous carrier medium and the hydrophobic surfaces of the pigment particles. Such a combination of disparate properties can be achieved with a pigment dispersant having distinct hydrophobic and hydrophilic polymeric segments or portions, i.e., having well defined polymer chain architecture. A wide variety of radically polymerizable monomers, such as methacrylate and acrylate monomers, are commercially available and can provide a wide range of properties including, for example, hydrophilic and hydrophobic properties. The use of conventional, i.e., non-living or free, radical polymerization methods to synthesize pigment dispersants provides little control over molecular weight, molecular weight distribution and, in particular, polymer chain structure. Aqueous pigment dispersions containing pigment dispersants prepared by conventional non-living radical polymerizations, typically have poor stability, e.g., the pigments re-agglomerate and/or settle out of the dispersion, and are unsuitable for the preparation of aqueous pigmented coatings compositions.
The continued development of aqueous pigment dispersions that are stable and suitable for the preparation of aqueous pigmented coating compositions is desirable. In particular, it would be desirable to develop aqueous pigment dispersions that comprise pigment dispersants having well defined polymer chain architecture in which distinct hydrophilic and hydrophobic polymer segments or portions are present.
U.S. Pat. Nos. 5,807,937, 5,789,487 and 5,763,548, and International Patent Publication No.'s WO 98/40415, WO 98/01480, WO 97/18247 and WO 96/30421 describe a radical polymerization process referred to as atom transfer radical polymerization (ATRP). The ATRP process is described as being a living radical polymerization that results in the formation of (co)polymers having predictable molecular weight and molecular weight distribution. The ATRP process is also described as providing highly uniform products having controlled structure (i.e., controllable topology, composition, etc.). The '937 and '548 patents also describe (co)polymers prepared by ATRP, which are useful in a wide variety of applications including, for example, dispersants and surfactants.
SUMMARY OF THE INVENTION
In accordance with the present invention, there is provided a pigment dispersion comprising:
(a) pigment;
(b) an aqueous carrier selected from water and a mixture of water and at least one organic solvent; and
(c) at least one pigment dispersant prepared by controlled radical polymerization of a polymerizable composition selected from,
(i) a prepolymer having a radically transferable group, and a polyfunctional monomer having at least two radically polymerizable ethylenically unsaturated groups, said prepolymer being prepared by controlled radical polymerization of at least one first monomer having a single radically polymerizable ethylenically unsaturated group in the presence of a monomeric initiator having at least one radically transferable group;
(ii) a star polymer having a plurality of radically transferable groups, and at least one second monomer having a single radically polymerizable ethylenically unsaturated group, said star polymer being prepared by the controlled radical polymerization of said prepolymer and said polyfunctional monomer, said first and second monomers being the same or different;
(iii) a core initiator having a plurality of radically transferable groups, and said first monomer, said core initiator being prepared by controlled radical polymerization of said polyfunctional monomer in the presence of said monomeric initiator; and
(iv) said first monomer and said polyfunctional monomer in the presence of said monomeric initiator; wherein upon the controlled radical polymerization of said polymerizable composition, said polyfunctional monomer or said core initiator forms substantially a core segment of said pigment dispersant, and said prepolymer or at least one of said first and second monomers forms substantially a plurality of arm segments of said pigment dispersant, each of said arm segments having hydrophobic and hydrophilic polymer chain segments.
The features that characterize the present invention are pointed out with particularity in the claims which are annexed to and form a part of this disclosure. These and other features of the invention, its operating advantages and the specific objects obtained by its use will be more fully understood from the following detailed description and the accompanying drawings in which pigment dispersants useful in embodiments of the invention are illustrated and described.
Other than in the operating examples, or where otherwise indicated, all numbers or expressions referring to quantities of ingredients, reaction conditions, etc, used in the specification and claims are to be understood as modified in all instances by the term “about.”
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patent: 5763548 (199
Coca Simion
O'Dwyer James B.
Franks James R.
Green Anthony
PPG Industries Ohio Inc.
Uhl William J.
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