Reduction of NOx emissions using a staged silver/alumina...

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine

Reexamination Certificate

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C423S213700, C423S239100, C423S239200

Reexamination Certificate

active

07396517

ABSTRACT:
The hydrocarbon-assisted, selective catalytic reduction of NOx constituents in lean-bum engine exhaust is benefited by passage of the exhaust over a staged catalyst bed comprising a first stage of an alumina-supported silver catalyst for oxidation of NO to NO2and partial oxidation of added hydrocarbon to an aldehyde. Downstream of the silver catalyst is a second catalyst selected for the reaction of hydrocarbon and aldehyde species with NO2to reduce it to nitrogen. Gamma-alumina and BaY zeolite are examples of suitable second stage catalysts.

REFERENCES:
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patent: 2006/0112678 (2006-06-01), Kaboord et al.
patent: 09-103649 (1997-04-01), None
Tatsuo Miyadera, Selective reduction of NOx by ethanol on catalysts composed of Ag/Al2O3 and Cu/TiO2 without . . . , Applied Catalysis B: Environmental 16 (1998), pp. 155-164.
Y. Yu, H. He, Q. Feng, H. Gao, X. Yang, Mechanism of the selective catalytic reduction of NOx by C2H5OH over . . . , Applied Catalysis B: Environmental 49 (2004), pp. 159-171.
L.-E Lindfors, K. Eranen, F. Klingstedt, D.Yu. Murzin, Silver/alumina catalyst for selective catalytic . . . , Topics in Catalysis vol. 28, Nos. 1-4, Apr. 2004, pp. 185-189.

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