Proppants containing dispersed piezoelectric or...

Wells – Processes – With indicating – testing – measuring or locating

Reexamination Certificate

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Details

C166S250100, C166S280200

Reexamination Certificate

active

08006754

ABSTRACT:
In one aspect, the invention relates to a method for “tagging” proppants so that they can be tracked and monitored in a downhole environment, based on the use of composite proppant compositions containing dispersed fillers whose electromagnetic properties change at a detectable level under a mechanical stress such as the closure stress of a fracture. In another aspect, the invention relates to composite proppant compositions containing dispersed fillers whose electromagnetic properties change under a mechanical stress such as the closure stress of a fracture. The currently preferred embodiments use substantially spherical thermoset nanocomposite particles where the matrix comprises a terpolymer of styrene, ethylvinylbenzene and divinylbenzene, a PZT alloy manifesting a strong piezoelectric effect or Terfenol-D manifesting giant magnetostrictive behavior is incorporated to provide the ability to track in a downhole environment, and carbon black particles possessing a length that is less than 0.5 microns in at least one principal axis direction may optionally be incorporated as a nanofiller.

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