Silver halide photographic emulsions containing benzimidazolocar

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Identified radiation sensitive composition with color...

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430505, 430574, 430576, 430588, 430589, G03C 726, G03C 732, G03C 110

Patent

active

045554811

ABSTRACT:
A silver halide photographic emulsion is disclosed which contains at least one of benzimidazolocarbocyanine dyes represented by the general formula (I) or (II): ##STR1## wherein a represents an integer of 1 to 8, R.sub.1, R.sub.2 and which may be identical with or different from one another, represent each --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, but at least one of R.sub.1, R.sub.2 and R.sub.3 contains an acid group-containing alkyl group, wherein b, which may be identical with or different from a, represents an integer of 1 to 8, l represents 0 or an integer of 1 to 8, and m represents 0 or an integer of 1 to 8, but l+m>0; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different from one another, represent each --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, but at least one of R.sub.4, R.sub.5 and R.sub.6 represents an acid group (for example, sulfo group or carboxyl group, etc.)-containing alkyl group; j represents 0 or an integer of 1 to 8; and k represents 0 or an integer of 1 to 8, but j+k>0; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8, which may be identical with or different from one another, represent each a hydrogen atom, a halogen atom, a substituted alkyl group, an unsubstituted alkyl group, an alkoxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group or a trifluoromethyl group; X represents an anion; and n represents 1 or 2 but represents 1 when the dye forms an inner salt.
The emulsion has good stability to the passage of time, in which an increase of fog under a high temperature or under a high temperature and a high humidity is controlled and reduction of sensitivity with the passage of time is minimized.

REFERENCES:
patent: 2739149 (1956-03-01), Van Lare
patent: 2912327 (1959-11-01), Maurer
patent: 2912329 (1959-11-01), Jones et al.
patent: 3769025 (1973-10-01), Ohkubo et al.
patent: 3988513 (1976-10-01), Matsuyama et al.
patent: 4179296 (1979-12-01), Sato et al.
Troitskaya, V. I. et al., "Cyanine Dyes Containing Fluorine XXVIII. Imidacyanine Dyes with Fluoroalkyl Groups at the Nitrogen Atoms of Benzimidazole", C.A. vol. 79, 54858k, 1973.

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