Conversion of fluorocarbons

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

Reexamination Certificate

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C570S172000

Reexamination Certificate

active

07928272

ABSTRACT:
A process is disclosed for the conversion of fluorocarbons into fluorinated unsaturated compounds useful as monomers or other chemical precursors, such as C2H2F2. The process comprises reacting a hydrocarbon feed (20) and a fluorocarbon feed (10) in a high temperature reactor (26), at sufficiently high temperature and sufficiently short resident time to form a reaction product mixture (28) having the fluorinated unsaturated compound as the major reaction product, and cooling (18) to a temperature sufficiently low to inhibit polymerization of the unsaturated compound. The reaction product may then be processed by removal of higher molecular weight compounds (35) and acids (32) and optionally separated (44) into product components.

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Li et al Chem.Eng.Sci., 2000, 55, 4067-4078.
Li, K., et al; “Experimental and computational studies of the pyrolysis of CBrF3, and the reaction of CBrF3with CH4”;Chemical Engineering Science, 55; pp. 4067-4078 (2000).
Examination Report dated Jan. 11, 2010, in counterpart Australian Patent Application No. 2004220475, 3 pages.
Tran et al., “Gas-Phase Reaction of Halon 1211 (CBrCIF2) with Methane,” Ind. Eng. Chem. Res., 2001, 40:3139-3143.

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