Catalyst with bimodal pore size distribution and the use...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making

Reexamination Certificate

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C502S064000, C502S068000, C502S072000, C502S080000, C502S087000, C502S241000, C502S263000, C502S341000, C502S347000, C502S348000, C502S349000, C502S350000, C502S351000, C502S415000, C502S439000

Reexamination Certificate

active

07977274

ABSTRACT:
The invention pertains to a catalyst useful for the epoxidation of an olefin. More particularly, the invention pertains to an improved catalyst useful for the epoxidation of ethylene to ethylene oxide. The catalyst has improved selectivity in the epoxidation process. The catalyst comprises a solid support having a surface, which has a first mode of pores which have a diameter ranging from about 0.01 μm to about 5 μm and having a differential pore volume peak in the range of from about 0.01 μm to about 5 μm. The surface then has a second mode of pores, different from the first mode of pores, which second mode of pores have a diameter ranging from about 1 μm to about 20 μm and have a differential pore volume peak in the range of from about 1 μm to about 20 μm. On the bimodal pore surface is a catalytically effective amount of silver or a silver-containing compound, a promoting amount of rhenium or a rhenium-containing compound, and a promoting amount of one or more alkali metals or alkali-metal-containing compounds.

REFERENCES:
patent: 3563914 (1971-02-01), Wattimena et al.
patent: 3692698 (1972-09-01), Riley et al.
patent: 3702259 (1972-11-01), Nielsen et al.
patent: 3962136 (1976-06-01), Nielsen et al.
patent: 4007135 (1977-02-01), Hayden et al.
patent: 4010115 (1977-03-01), Nielsen et al.
patent: 4010155 (1977-03-01), Inouye et al.
patent: 4012425 (1977-03-01), Nielsen et al.
patent: 4039561 (1977-08-01), Mitsuhata et al.
patent: 4066575 (1978-01-01), Winnick
patent: 4123385 (1978-10-01), Rebsdat et al.
patent: 4168247 (1979-09-01), Hayden et al.
patent: 4242235 (1980-12-01), Cognion et al.
patent: 4301037 (1981-11-01), Sanchez et al.
patent: 4350616 (1982-09-01), Boussert
patent: 4740493 (1988-04-01), Boehning et al.
patent: 4761394 (1988-08-01), Lauritzen
patent: 4766105 (1988-08-01), Lauritzen
patent: 4808738 (1989-02-01), Lauritzen
patent: 4820675 (1989-04-01), Lauritzen
patent: 4829043 (1989-05-01), Boehning et al.
patent: 4833261 (1989-05-01), Lauritzen
patent: 4908343 (1990-03-01), Bhasin
patent: 5011807 (1991-04-01), Hayden et al.
patent: 5057481 (1991-10-01), Bhasin
patent: 5099041 (1992-03-01), Hayden et al.
patent: 5102848 (1992-04-01), Soo et al.
patent: 5187140 (1993-02-01), Thorsteinson et al.
patent: 5387751 (1995-02-01), Hayden et al.
patent: 5407888 (1995-04-01), Herzog et al.
patent: 5504052 (1996-04-01), Rizkalla et al.
patent: 5504053 (1996-04-01), Chou et al.
patent: 5507956 (1996-04-01), Bonse et al.
patent: 5518979 (1996-05-01), Bonse et al.
patent: 5703001 (1997-12-01), Rizkalla
patent: 5733842 (1998-03-01), Gerdes et al.
patent: 5750461 (1998-05-01), Engelhardt et al.
patent: 5773657 (1998-06-01), Rutter et al.
patent: 5801259 (1998-09-01), Kowaleski
patent: 5935897 (1999-08-01), Trubenbach et al.
patent: 5935898 (1999-08-01), Trubenbach et al.
patent: 6245698 (2001-06-01), Pope et al.
patent: 6299995 (2001-10-01), Abdo et al.
patent: 6571214 (2003-05-01), Newman et al.
patent: 6573214 (2003-06-01), Abdo et al.
patent: 6670303 (2003-12-01), Heineke et al.
patent: 6831037 (2004-12-01), Szymanski et al.
patent: 6984310 (2006-01-01), Ginestra et al.
patent: 7102022 (2006-09-01), Evans et al.
patent: 7186757 (2007-03-01), Espinoza et al.
patent: 7247600 (2007-07-01), Lockemeyer
patent: 7259129 (2007-08-01), Matusz et al.
patent: 7348444 (2008-03-01), Evans et al.
patent: 7388119 (2008-06-01), Bottcher et al.
patent: 7449496 (2008-11-01), Jin et al.
patent: 7479565 (2009-01-01), Yeates et al.
patent: 7507844 (2009-03-01), Pak
patent: 7538235 (2009-05-01), Lockemeyer
patent: 7547795 (2009-06-01), Matusz et al.
patent: 7553795 (2009-06-01), Bortinger et al.
patent: 7615654 (2009-11-01), Le-Khac et al.
patent: 7671222 (2010-03-01), Kaminsky et al.
patent: 2002/0004452 (2002-01-01), Abdo et al.
patent: 2002/0091291 (2002-07-01), Nakashiro
patent: 2003/0144141 (2003-07-01), Bowman et al.
patent: 2004/0170556 (2004-09-01), Szymanski et al.
patent: 2004/0198992 (2004-10-01), Matusz et al.
patent: 2004/0260103 (2004-12-01), Matusz et al.
patent: 2005/0096219 (2005-05-01), Szymanski et al.
patent: 2005/0107479 (2005-05-01), Espinoza et al.
patent: 2007/0111886 (2007-05-01), Serafin et al.
patent: 2007/0149792 (2007-06-01), Zhang et al.
patent: 2007/0184973 (2007-08-01), Lockemeyer et al.
patent: 2008/0015393 (2008-01-01), Matusz et al.
patent: 2008/0081920 (2008-04-01), Guekcel
patent: 2008/0125610 (2008-05-01), Lockemeyer et al.
patent: 2 432 200 (2002-07-01), None
patent: 0352850 (1990-01-01), None
patent: 0480538 (1992-04-01), None
patent: 0501317 (1992-09-01), None
patent: 1074301 (2001-02-01), None
patent: 1458698 (2005-04-01), None
patent: WO02/051547 (2002-07-01), None
patent: WO2004078737 (2004-09-01), None
patent: 2006133183 (2006-12-01), None
patent: 2006133187 (2006-12-01), None
International Search Report and Written Opinion dated Aug. 13, 2010.
Request for Inter Partes Re-examination for U.S. Appl. No. 7,507,845 issued in a related U.S. Patent Application, namely U.S. Serial No. 95/001,445, together with its attachments.
Re-Examination Non-Final Office Action dated Dec. 7, 2010 in a related U.S. Patent Application, namely U.S. Serial No. 95/001,445.
Office Action received in a related U.S. Patent Application, namely U.S. Appl. No. 12/360,482.
Horvath, I. T., “Encyclopedia of Catalysis, Epoxidation —Industrial” (“Encyclopedia of Catalysis”), 2003, vol. 3, pp. 246-264, Wiley-Interscience.
Third Party Requester's Comments to Patent Owners Reply of Feb. 7, 2011 Pursuant to 37 C.F.R. § 1.947 for U. S. Patent 7,507,845 together with attachments.

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