Method for determining a gas compositional origin from...

Data processing: measuring – calibrating – or testing – Measurement system in a specific environment – Chemical analysis

Reexamination Certificate

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C702S030000, C702S011000, C702S179000

Reexamination Certificate

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07979216

ABSTRACT:
At least one type of carbon material susceptible to generate a gas G is selected. Then, a model is built from the carbon isotopic composition of a gas P generated by thermal degradation of this type of carbon material. The model is calibrated by calibrating the kinetic effect independently of the precursor effect. In order to achieve that, pyrolyses are performed on compounds modeling the type of carbon material, said compounds being synthesized and labeled with13C. Using said model, a carbon isotopic composition of gas P generated is estimated. Finally, it is determined whether gas G has been generated from the selected type of carbon material, by comparing a measured isotopic composition of gas G to the estimated isotopic composition.

REFERENCES:
patent: 7153688 (2006-12-01), Mango
French Search report, FR 0703262, Jan. 4, 2008.
F. Mango, et al., “The carbon isotopic composition of catalytic gas: A comparative analysis with natural gas”, Geochimica et Cosmochimica Acta, vol. 63, No. 7/8, pp. 1097-1106, Jan. 1999.
F. Behar, et al., “Thermal Evolution of Crude Oils in Sedimentary Basins: Experimental Simulation in a Confined System and Kinetic Modeling”, Revue de L'Institut Francais du Petrole, vol. 46, No. 2, Mar.-Apr. 1991.
F. Behar, et al., “Thermal Stability of Source Rock and Oil Asphaltenes: Comparison With Kerogen Kinetics in Open System Pyrolysis”, IV ALAGO Workshop—Basin Modeling, Oct. 16-19, 2005.
F. Lorant, et al., “Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases”, Chemical Geology 147 (Jan. 1998)pp. 249-264.
A. Prinzhofer, et al. “Gas Isotopes Tracing: An Important Tool for Hydrocarbons Exploration”, Oil & Gas Science and Technology—Rev. IFP, vol. 58 (2003), No. 2, pp. 299-311.

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