Process for producing fine particles of solid solution

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

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Details

C502S303000, C502S304000, C502S202000

Reexamination Certificate

active

07994090

ABSTRACT:
Provided is a process for readily producing fine particles of a solid solution having a small particle size, comprising a solid solution of zirconia, ceria and a rare earth oxide in a desired composition, and being highly crystalline.The process for producing the fine particles of the solid solution comprises the following steps in the order named: obtaining a melt comprising, in terms of mol % on an oxide basis, from 5 to 50% ZrO2, CeO2and RE2O3(where RE is at least one member selected from rare earth elements other than Ce) in total, from 10 to 50% RO (where R is at least one member selected from the group consisting of Mg, Ca, Sr, Ba and Zn), and from 30 to 75% B2O3; quenching the melt to obtain an amorphous material; heating the amorphous material to obtain precipitates containing crystals of a solid solution with ZrO2, CeO2and RE2O3; and separating the crystals of the solid solution from the precipitates to obtain fine particles of the solid solution.

REFERENCES:
patent: 4565792 (1986-01-01), Knapp
patent: 7381232 (2008-06-01), Beppu et al.
patent: 60-065726 (1985-04-01), None
patent: 01-239038 (1989-09-01), None
patent: 11-292538 (1999-10-01), None
patent: 11-292539 (1999-10-01), None
patent: 2000-319019 (2000-11-01), None
patent: 2004-331492 (2004-11-01), None
patent: 2007-326735 (2007-12-01), None
patent: 2009-075022 (2009-06-01), None
U.S. Appl. No. 12/796,492, filed Jun. 8, 2010, Beppu, et al.

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