Production of unsaturated amines employing a palladium compound

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252431C, 252431N, 252431P, 26029351, 2603268, 260563R, 260563C, 260577, 260583H, 26583P, 260585D, 544178, 544404, C07C 8518, C07C 8745, C07C 8754, C07C 8762

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041001940

ABSTRACT:
N-(alkadienyl)amines are produced at a rapid rate and in high yield by the reaction of conjugated dienes with ammonia and amines in a hydroxylic solvent using a catalyst system comprising a palladium compound co-catalyzed with a phosphonite ligand.

REFERENCES:
patent: 3502725 (1970-03-01), Dewhirst et al.
Baker et al., "J. Chem. Soc., Perkin Trans. 2," pp. 1511-1517 (1974).

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