Preparation of urethane products

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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546226, 548531, 560 27, 560 32, 560114, 560157, 560162, C07D26530, C07D21106, C07D20710, C07C26904

Patent

active

050555774

ABSTRACT:
The present invention provides a process for preparing urethanes from primary or secondary amines, carbon dioxide and a diolefin. The amine is reacted with carbon dioxide to form the ammonium carbamate salt which is then reacted with a stoichiometric amount of a diolefin coordinated to palladium(II).

REFERENCES:
patent: 4467089 (1984-09-01), Bechara
patent: 4945179 (1990-07-01), Drent
Chemistry Express, vol. 1, No. 4, pp. 224-227 (1986) Kinki Chemical Society, Japan.

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