Polymerization of CO/olefin with phosphorus bidentate ligand-sol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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502162, 524612, 525123, 525127, 525292, 525301, 525539, 568 8, 568 17, C08G 6702

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050555529

ABSTRACT:
An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, an anion of a strong non-hydrohalogenic acid and a supported bidentate ligand of phosphorus. The improved process is characterized by a reduced level of reactor fouling. The polymer products are useful as engineering thermoplastics.

REFERENCES:
patent: 3694412 (1972-09-01), Nozaki
patent: 4940776 (1990-07-01), Bakkum et al.

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