Process for producing gamma-butyrolactone

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D30732

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040012824

ABSTRACT:
Gamma-Butyrolactone is produced by passing vaporized maleic acid/anhydride or succinic acid/anhydride or mixtures thereof, water, and hydrogen, over a metallic catalyst capable of hydrogenolyzing a carboxylic group to a methyleneoxy group. Even though water is also a byproduct of the reaction, very high yields of gamma-butyrolactone are obtained, and the added water plays a key role in extending catalyst life by suppressing the formation of coke and tar.

REFERENCES:
patent: 2072861 (1937-03-01), Amend et al.
patent: 3065243 (1962-11-01), Dunlop et al.
patent: 3758512 (1973-09-01), Hanetaka et al.

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