Method for making aromatic bis(ether anhydrides)

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D30789

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043405452

ABSTRACT:
A method is provided for making aromatic bis(ether phthalic anhydride)s by effecting an imide-anhydride exchange between aromatic bis(ether N-organophthalimide) and phthalic anhydride in the presence of an imide anhydride exchange catalyst and water and extracting the aqueous imide-anhydride exchange reaction mixture with an inert organic solvent. Imide-anhydride exchange product having at least 97 mole percent aromatic bis(ether phthalic anhydride) can be made at substantially reduced temperatures and pressures, by increasing by a factor of at least two, the number of times the imide-anhydride exchange mixture is extracted.

REFERENCES:
patent: 4116980 (1978-09-01), Webb
patent: 4128574 (1978-12-01), Markezich et al.
Weissberger, Technique of Organic Chem., vol. III, Part I: Separation Purification; Interscience Publishers, (1956), pp. 149-157, 164 and 313.

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