Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Process of making developer composition
Reexamination Certificate
2000-05-16
2001-09-11
Goodrow, John (Department: 1753)
Radiation imagery chemistry: process, composition, or product th
Electric or magnetic imagery, e.g., xerography,...
Process of making developer composition
C430S110300
Reexamination Certificate
active
06287742
ABSTRACT:
FIELD OF THE INVENTION
This invention generally relates to toner compositions and a method of producing toners for developing latent electrostatic images in electrophotography, electrostatic recording and electrostatic printing. More specifically, this invention relates in a preferred embodiment to a method of forming suitably sized resin particles which incorporate coloring agents and other components therein for high-resolution color electrophotography, electrostatic recording and electrostatic printing. Preferred resins include amorphous polyesters and ethylene
orbornene copolymers.
BACKGROUND OF THE INVENTION
The formation and development of images on the surface of photoconductive materials by electrostatic means is well known. The basic electrophotographic imaging process (U.S. Pat. No. 2,297,691) involves placing a uniform electrostatic charge on a photoconductive insulating layer known as a photoconductor or photoreceptor, exposing the photoreceptor to a light and shadow image to dissipate the charge on the areas of the photoreceptor exposed to the light, and developing the resulting electrostatic latent image by depositing on the image a finely divided electroscopic toner material. The toner will normally be attracted to those areas of the photoreceptor which retain a charge, thereby forming a toner image corresponding to the electrostatic latent image. This developed image may then be transferred to a substrate such as paper. The transferred image subsequently may be permanently affixed to the substrate by heat, pressure, a combination of heat and pressure, or other suitable fixing means such as solvent or over coating treatment.
Also well known are techniques to develop such electrostatic images. Developer is a vehicle in which are dispersed charged colored toner particles. The photoreceptor bearing the electrostatic latent image is contacted with the developer. The contact causes the charged toner particles in the developer to migrate to the charged areas of the photoreceptor to develop the latent image. Then, the photoreceptor is developed with the charged colored particles adhering to the latent image in image configuration. The developed image is then typically transferred to a suitable substrate, such as paper or transparency material, and optionally may be fixed to the substrate by heat, pressure or other suitable means.
Electrostatic images formed on an electrophotographic photoconductor and an electrostatic recording medium are generally developed by using (i) a mono-component type dry developer consisting of a toner comprising a coloring agent such as a dye or pigment and a binder resin in which the coloring agent is dispersed, or with addition of a charge controlling agent thereto when necessary, or (ii) a two-component type dry developer comprising the above-mentioned toner and solid carrier particles. Toners and developer compositions including colored particles are well known. In this regard, see U.S. Pat. Nos.: 5,352,521; 4,778,742; 5,470,687; 5,500,321; 5,102,761; 4,645,727; 5,437,953; 5,296,325 and 5,200,290 the disclosures of which are hereby incorporated by reference. The traditional compositions normally contain toner particles consisting of resin and colorants, wax or a polyolefin, charge control agents, flow agents and other additives. A typical toner formulation generally contains about 90-95 weight percent resin, about 2-10 weight percent colorant, 0-about 6 weight percent wax, 0-about 3 weight percent charge control agent, about 0.25 -1 weight percent flow agent and 0-about 1 weight percent other additives. Major resins are styrene-acrylic copolymers, styrene-butadiene copolymers and polyesters. The colorants usually are selected from cyan dyes or pigments, magenta dyes or pigments, yellow dyes or pigments, and mixtures thereof.
Conventional color toners are produced by a milling process described, for example, in the aforementioned U.S. Pat. No, 5,102,761. In that process, a polyacrylate resin is compounded with pigments, charge control agents (“CCA”) and occasionally wax in a melt mixer. The resulting polymer mixture is mechanically crushed and then milled into small particles. The conventional toner particles typically have an irregular shape and a broad distribution in particle size. For optimum resolution of images and color, smaller particles perform better. Thus, for example, it is difficult to obtain resolutions better than about 600 dots/inch when the average particle size is more than about 7 &mgr;m. For resolutions in the order of about 1200 dots/inch, particle sizes smaller than 5 &mgr;m are typically needed. It is difficult to make particles smaller than about 7-10 &mgr;m by conventional processes because of the high energy cost of producing small particles as well as uniform narrow particle size distribution.
Improvements to cure such deficiencies have been attempted in the past. For example, the aforementioned U.S. Pat. Nos. 5,352,521, 5,470,687 and 5,500,321 disclose toner particles produced by dispersion polymerization. In such method, monomers (typically styrenic and acrylate monomers) and additives such as pigments, CCA and wax are mixed together to form a dispersion. This is then further dispersed into an aqueous or a non-aqueous medium and the monomers are reacted to form toner particles. This method has the advantage over other methods that spherical toner particles with a small diameter can be prepared by a single process. However, the polymerization involves a substantial volume contraction and it results in entrapment of the dispersion medium inside the toner particles. Furthermore, the polymerization is difficult to be brought to completion and a substantial portion of the monomers remains in the toner particles. The residual monomers and the entrapped dispersion solvent are difficult to separate from the particles. Also, the polarity of the polymerizing materials changes drastically in the course of the polymerization and the additives tend to exude from the particle bulk and tend to concentrate on the surface thereof. Further, agents employed, such as dispersion-stabilizing agent and surface active agent, which cause the charging characteristics and preservability of the toner particles to deteriorate, remain on the surface of the toner particles, and those agents are extremely difficult to remove from the toner particles.
There is continuing interest in the development of new and improved methods of producing toners for application in high-resolution color electrophotography. Accordingly, an object of the present invention is to provide a method of producing high-resolution color toner which has a superior combination of properties for electrophotographic imaging systems by dispersing a pigment and other additives in a polymer resin and forming spherical toner particles with a small diameter by dispersing a compounded polymer resin in a dispersion medium including a surfactant under a vigorous shearing condition.
Other objects and advantages of the present invention shall become apparent from the accompanying description and examples.
SUMMARY OF THE INVENTION
There is provided in accordance with one aspect of the present invention a process for preparing a particulate toner composition for developing latent electrostatic images including the steps: (a) preparing a first particulate resin composition including a resin component and a pigment component, and optionally including a charge control agent; (b) dispersing the first particulate pigmented resin composition in an organic medium including a surfactant, wherein the resin is substantially insoluble in the organic medium; (c) comminuting the first particulate resin composition in the organic medium by way of application of shear thereto at an elevated temperature; and (d) recovering the comminuted particulate toner composition from the organic medium. In a particularly preferred aspect, the toner particles are substantially spherical in shape and have a volume average diameter in the range of from about 1 to about 10 microns with at least 95 percent of the par
Ferrell Michael W.
Goodrow John
MatSci Solutions, Inc.
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