Method of crystallizing aluminium sulphate solutions to form dus

Chemistry: physical processes – Physical processes – Crystallization

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23305A, B01D 902

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active

042760526

ABSTRACT:
A method of crystallizing a solution of aluminium sulphate to form crystal agglomerates having an essentially uniform grain size and being in the form of granules having a characteristic appearance and good storage properties. A solution having a temperature of 105.degree.-115.degree. C. and a concentration of 14.5-16.8% by weight of Al.sub.2 O.sub.3 is brought to crystallize onto a bed of crystalline aluminium sulphate in a drum, the length of which is considerably larger than the diameter, a temperature of 70.degree.-95.degree. C. being maintained in the bed. Part of the crystalline product discharged from the drum is ground and recycled to the drum in an amount of 40-200 percent by weight of added solution and air is passed through the drum to remove moisture evolved by the crystallization so as to form a final product with more than 75% by weight present in the crystalline state and containing 15.0-18.0% by weight of Al.sub.2 O.sub.3.

REFERENCES:
patent: 2340567 (1944-02-01), Sargent
patent: 2895813 (1959-07-01), Brooksbank et al.
patent: 3011878 (1961-12-01), Lackey et al.
patent: 3082064 (1963-03-01), Brooksbank
patent: 3141743 (1964-07-01), Marsh
patent: 3143392 (1964-08-01), Saeman
J. Am. Chem. Soc. (1954), 2057, Smith et al.

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