Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1979-07-23
1981-03-24
Garner, Vivian
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
260550, 560263, 568858, 568859, 585641, C07C 6700, C07C 6914, C07C 6924
Patent
active
042582083
ABSTRACT:
A process for the preparation of 2-bromoalkyl esters and vicinal glycol esters which comprises thermally decomposing at temperatures of from 100.degree. C. to 200.degree. C. an organic bromoalkyl tellurium compound selected from 2-bromoalkyltellurium tribromide or bis(2-bromoalkyl)tellurium dibromide, wherein the alkyl group is ethyl, propyl or butyl, in a carboxylic acid having from 1 to 4 carbon atoms which is employed as solvent as well as to supply the ester moiety to the esters produced. The esters may be converted to the respective glycol with water or an aqueous base.
REFERENCES:
patent: 3668239 (1972-06-01), Kallar
Ogawa et al., Bull. Chem. Soc., Japan, vol. 41, p. 3031, (1968).
Kao Jar-lin
Sheng Ming N.
Atlantic Richfield Company
Garner Vivian
McCaslin Delbert E.
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