Process for the production of tertiary 2-haloacetamides

Details Process for the production of tertiary 2-haloacetamides Process for the production of tertiary 2-haloacetamides

1979-08-02

1981-03-24

Waltz, Thomas A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

260326N, 2603473, 564182, 260465D, 564191, 564209, 564210, 564212, 548212, 560155, 560172, C07C10200, C07D27762

Patent

active

042581966

ABSTRACT:
The disclosure herein relates to a novel process for producing tertiary 2-haloacetamides by reacting primary or secondary 2-haloacetamides with an agent capable of generating an anion of the primary or secondary 2-haloacetamide under base conditions and alkylating the anion of the 2-haloamide with an alkylating agent; said anion is generated, for example, by electrolysis or by metals, metal hydrides, fluorides, oxides, hydroxides, carbonates, phosphates, or alkoxides.

REFERENCES:
patent: 3992432 (1976-11-01), Napier et al.
Kakimoto et al., Chemistry Letters, pp. 47-48 (1976).
Sorel et al., J. Org. Chem. 23 pp. 330-331 (1958).

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