Selective cracking of disubstituted benzenes having polar substi

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568 27, 568 28, 568 38, 568324, 568576, 568939, 568949, 568751, 564183, 564272, 564424, 562494, 560103, 260453A, 260454, 260465B, 568438, 570190, 570211, C07C 3786, C07C 1738, C07C 4585, C07C 8526

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043717217

ABSTRACT:
A process for selective cracking of 1,4-disubstituted benzene compounds having at least one polar substituent. Mixtures containing isomers of such a compound are brought into contact with a specified type of shape selective crystalline zeolite catalyst under conditions of temperature and pressure conducive to reaction of said benzene compound, thereby selectively reacting the 1,4-disubstituted isomer in preference to the 1,2- and 1,3-disubstituted isomers of said polar benzene compound. The shape selective zeolite catalysts employed herein are crystalline zeolites characterized by a silica to alumina ratio of at least about 12 and a constraint index within the approximate range of 1 to 12.

REFERENCES:
patent: 3856873 (1974-12-01), Burress
patent: 4163028 (1979-07-01), Tabak et al.
patent: 4181811 (1980-01-01), Young
patent: 4197413 (1980-04-01), Kaeding et al.
patent: 4205189 (1980-05-01), Young et al.
patent: 4230894 (1980-10-01), Young

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