Process for replacing the hydroxy group of an aromatic hydroxy c

Details Process for replacing the hydroxy group of an aromatic hydroxy c Process for replacing the hydroxy group of an aromatic hydroxy c

1974-05-31

1976-06-01

Horwitz, D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252430, C07C 8506

Patent

active

039609626

ABSTRACT:
Aromatic hydroxy compounds (e.g., 2,6-dimethylphenol) are converted to the corresponding aromatic amine (e.g., 2,6-dimethylaniline) by reaction with ammonia at elevated temperatures in the presence of a cyclohexanone promoter and a catalyst comprising metallic palladium bonded to a phosphinated polystyrene resin.

REFERENCES:
Bruner et al., Inorg. Chem., 12(7), 1465-1470, (1973).
Grubbs et al., J. Am. Chem. Soc. 93, 3062-3063, (1971).

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