Process for preparing polyfluoroalkyl-substituted compounds

Details Process for preparing polyfluoroalkyl-substituted compounds Process for preparing polyfluoroalkyl-substituted compounds

1984-01-26

1991-05-21

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556413, 556415, 556419, 556427, 556436, 556440, 556470, 556476, 570135, 570136, 570137, 570153, 570154, 570172, 570175, 20415763, 20415764, 20415765, 564192, 564193, 564199, 564204, 564209, 564463, 564502, 564509, 564510, 568 39, 568 41, 568 42, 568 43, 568 44, 568 56, 568307, 568382, 568416, 568495, 568417, 568418, 568419, 568589, 568683, 568684, 568685, 558357, 558359, 560156, 560160, 560161, 560174, 560183, 560205, 560226, 560227, C07F 708, C07F 710, C07F 718, C07F 2118

Patent

active

050177184

ABSTRACT:
A process for preparing a perfluoroalkyl-substituted compound is disclosed. The process comprises reacting a halopolyfluoroalkane having 1 to 20 carbon atoms with a compound selected from the group consisting of (1) a substituted or unsubstituted ethylene, (2) a substituted or unsubstituted acetylene and (3) a substituted or unsubstituted allylsilane, in the presence of a metal-carbonyl complex of the metal of the Group VIII of the Periodic Table. Alternatively, the reaction between the halopolyfluoroalkane and the substituted or unsubstituted allylsilane is effected under radical generating condition.

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