Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1977-04-11
1978-09-12
Helfin, Bernard
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
252438, C07C 6705
Patent
active
041139704
ABSTRACT:
1,4-Diacyloxybutene-2 is produced with a high yield by reacting 1,3-butadiene with a carboxylic acid, for example, acetic acid, and molecular oxygen in the presence of a catalyst containing metallic palladium and at least one iodine-containing substance selected from the group consisting of iodine, iodic acid, iodates, for example, alkali metal iodates and substituted and unsubstituted ammonium iodate, and iodides, for example, hydrogen iodide, alkali metal iodide and substituted and unsubstituted ammonium iodides, the ratio in gram-atom, of iodine to palladium in the above-mentioned catalyst being 0.1 to 1.5:1.
REFERENCES:
patent: 3671577 (1972-06-01), Ono
Ikeda Masanori
Tamura Nobuhiro
Tanabe Masanori
Asahi Kasei Kogyo Kabushiki Kaisha
Helfin Bernard
Shippen Michael
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