Synthesis of prostaglandin precursors

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260429R, C07F 1500

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active

041137558

ABSTRACT:
A process of making prostaglandin precursors by reacting bicyclic or polycyclic olefins with an alkenylmercuric salt, in the presence of a noble metal salt to provide a cis, beta-alkenyl bicyclic alkyl noble metal salt.

REFERENCES:
patent: 3369035 (1968-02-01), Schultz
patent: 3398168 (1968-08-01), Medema
patent: 3446825 (1969-05-01), Schultz
patent: 3705919 (1972-12-01), Heck
patent: 3783140 (1974-01-01), Heck
patent: 4065479 (1977-12-01), Larock
Horino et al., Tetrahedron Letters, No. 8, pp. 647-650, (1974).

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