Process for 3,5-di-tert-butylsalicylaldehyde

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3711, C07C 3906

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active

053248600

ABSTRACT:
A process for the synthesis of 3-5-tert-butylsalicylaldehyde from 2,4-di-tert-butylphenol and hexamethylenetetramine is disclosed. The reaction provides 3,5-tert-butylsalicylaldehyde in commercially attractive yields from readily available starting materials.

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patent: 4009210 (1977-02-01), Cahoy
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Komissarova et al. "Anomalous Duff reaction with 2,4-di-tert-butylphenol" Chem. Abs. 110:212723c (1988).
Yahagi, Nobuo "Reaction of 2,4-dimethylphenol with hexamethylenetetramine" Chem. Abs. 93:8106e (1978).
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