Superior high solids coatings

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524853, 524902, 526216, C08F 206, C08F 2028, C08K 510

Patent

active

045322945

ABSTRACT:
According to one aspect of the present invention, an improved method for preparing acrylic copolymer resins is provided in which the polymerization solvent comprises an alkanoic acid alkyl ester having a total of from about 7 to 12 carbon atoms per molecule. The monomers comprise hydroxy-substituted alkyl (meth)acrylates, and non-hydroxy substituted alkyl (meth)acrylates, and the process provides an improved method for forming low molecular weight acrylic resins useful as components in high solids acrylic coatings suitable for electrostatic spraying. The polymerization solvent can remain in the resin to become the solvent employed in the higher solids coating containing the thus-formed acrylic resins and provides surprisingly improved electrical resistivity and solvency and decreased surface tensions over prior art polymerization solvents. In accordance with another aspect of the present invention, an improved method for preparing high solids acrylic resin coatings is provided wherein an acrylic copolymer resin is dissolved in a coating solvent comprising at least one alkyl alkanoic acid ester having a total of from 7 to 12 carbon atoms per molecule.

REFERENCES:
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patent: 3348965 (1967-10-01), Drum
patent: 3796590 (1974-03-01), Spiller
patent: 3883453 (1975-05-01), Takahashi
patent: 4151152 (1979-04-01), Schmitt et al.
patent: 4276212 (1981-06-01), Khanna
K. K. Mitra, "Electrostatic Application of Paint", Paint India, vol. 29, No. 9, pp. 52-56 (1979).
"Hexyl Acetate for the Coatings Industry", Enjay Chemical Company, German Patent Application No. 1519258.
"Primary Amyl Acetate--A Unique Solvent for Paints Applied by Electrostatic Spray", Union Carbide Corporation.
"Acrylic Copolymer Oligomers for High Solids Coating Resins", D. Rhum et al., vol. 55, No. 703, Aug. 1983.

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