Process for preparing alkyl- or arylphosphonothioic dihalides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 934, C07F 904

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active

041305833

ABSTRACT:
Alkyl- or arylphosphonothioic dihalides are prepared by contacting a dialkyl or diaryl thioether with various phosphorus containing reactants including: PCl.sub.3, PBr.sub.3, P(S)Cl.sub.3, P(S)Br.sub.3, P.sub.4 S.sub.3, P.sub.4 S.sub.5, P.sub.4 S.sub.7, P.sub.4 S.sub.1 O and elemental phosphorus under at least autogenous pressure at a temperature of from about 200.degree. C. to about 400.degree. C. The compounds obtained are useful as constituents in insecticides, fungicides, pharmaceuticals, and as intermediates in preparation of other organophosphorus compounds.

REFERENCES:
patent: 3457305 (1969-07-01), Baker et al.
patent: 3457307 (1969-07-01), Groenweghe et al.

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