Process for polymerization of vinyl monomers with improved kinet

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526210, 526212, C08F 238, C08F 220

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active

044826842

ABSTRACT:
This invention relates to the use of an organic compound which is a polymerization inhibitor in aqueous suspension polymerization systems for making polymers from olefinic monomers. The inhibitor is added to the aqueous medium prior to the start of or during the reaction. Its use allows a wide range of control throughout the increased reaction rate region and substantially reduces the tailpeak encountered during the aqueous suspension polymerization of olefinic monomers. One example of a suitable inhibitor is 2,2'- methylene bis (4,6-di-tertiary butylphenol).

REFERENCES:
patent: 3225108 (1965-12-01), Sturgis
patent: 3502269 (1970-03-01), Matthews
patent: 3642756 (1972-02-01), Meeks
patent: 4245073 (1981-01-01), Noel

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