Process for preparation of .beta.-alkenyltrimethylsilanes

Details Process for preparation of .beta.-alkenyltrimethylsilanes Process for preparation of .beta.-alkenyltrimethylsilanes

1996-01-31

1996-10-22

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556468, C07F 708

Patent

active

055678343

ABSTRACT:
A process for making .beta.-alkenyltrimethylsilanes and trimethylsilyl carboxylates. The process comprises contacting a mixture comprising hexamethyldisilane and an alkene carboxylate having a .beta.-unsaturated carbon atom with novel organo-palladium and organo-nickel complexes, as catalysts, at a temperature within a range of about 100.degree. C. to 250.degree. C. The present process is especially useful for making allyltrimethylsilane and trimethylsilyl acetate.

REFERENCES:
patent: 2787627 (1957-04-01), Kuriyagawa et al.
patent: 4604477 (1986-08-01), Rich
patent: 5187291 (1993-02-01), Seiler et al.
Urata et al., Bull, Chem. Soc. Jpn. 57:607-608 (1984).

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