Preparation of alcohols and ethers

Details Preparation of alcohols and ethers Preparation of alcohols and ethers

1974-04-17

1976-01-06

Moatz, Harry I.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260611A, 260611B, 260614R, 260615R, 260615B, 260618R, 260639R, 260640, C07D30706, C07C 4100, C07C 2100, C07C 2912

Patent

active

039312380

ABSTRACT:
Alcohols and ethers are prepared by reacting a substituted hydrocarbon compound containing halogen or alkyl sulfate groups with an alkali metal hydroxide, in aqueous solution, in the presence of a catalytic amount of certain betaines and recovering from the reaction mixture the desired alcohol and/or ether. The reaction mixture can contain alcohols, ethers, and diethers, in varying amounts, depending on reactants and reaction conditions. Typical examples of materials used are: 1,4-dichlorobutane, sodium hydroxide, and tridodecylcarbomethoxymethyl ammonium bromide as the catalyst. The ethers are useful as solvents.

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