Conversion of tetrahydropyrimidines to pyridines

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260283SY, 260297R, C07D21304

Patent

active

039311910

ABSTRACT:
A process of converting 2,3,4,5-tetrahydropyrimidines containing at least 1 hydrogen in the 2-position and at least one methylene group in the 4-position to corresponding pyridines which comprises heating said tetrahydropyrimidines to a temperature sufficiently high to remove ammonia and hydrogen so as to form said pyridines.

REFERENCES:
asinger et al., Angew. Chem., Vol. 70, p. 680-681, (1958).

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