Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o

Details Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o

1996-04-12

1997-05-27

Ivy, C. Warren

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30114

Patent

active

056333919

ABSTRACT:
A process for the epoxidation of olefins comprises contacting the olefin with bis(trimethylsilyl)peroxide in the presence of a rhenium catalyst in an organic solvent.

REFERENCES:
patent: 5155247 (1992-10-01), Herrmann et al.
patent: 5166372 (1992-11-01), Crocco et al.
Irie, R. et al., "Enantioselective Epoxidation of Chromene Derivatives Using Hydrogen Peroxide as a Terminal Oxidant", Synlett, 4, pp. 255-256, 1994.
Herrmann, W. A., et al., "Methyltrioxorhenuim as a Catalyst for Olefin Oxidation", Angew. Chem. Int. Ed. Engl., 30(12), pp. 1638-1641, 1991.
Adam, Waldemar and Mitchell Caterine M., "Methyltrioxorhenium (VII)-Catalyzed Epoxidation of Alkenes with the Urea/Hydrogen Peroxide Adduct", Amgew. Chem. Int. Ed. Engl. 1996, 35, No. 5, pp. 533-534.
"Epoxidation of Allyl and Homoallyl Trimethylsilyl Ethers with t-Butyldioxytrimethylsilane and Silicon Lewis Acid/Vanadium Catalyst", Tamejiro Hiyama, et al., Tetrahedron Letters, vol. 24, No. 4, pp. 395-398, 1983.
"Enantioselective Epoxidation of Chromene Derivatives Using Hydrogen Peroxide as a Terminal Oxidant", Ryo Irie, et al., Synlett, (1994), pp. 255-256.
"Methyltrioxorhenium as a Catalyst for Olefin Oxidation", Wolfgang A. Herrmann, et al., Angew. Chem. Int. Ed. Engl. 30 (1991), No. 12, pp. 1638-1641.
"Dissociation of Hydrogen Peroxide Adducts in Solution: The Use of Such Adducts for Epoxidation of Alkenes", Antonio M. d'A. Rocha Gonsalves, et al., J. Chem. Research (S), (1991) pp. 208-209.
"A Very Simple Oxidation of Olefins and Ketones with UHP-Maleic Anhydride", Luis Astudillo, et al., Heterocycles, vol. 36, No. 5, 1993, pp. 1075-1080.

Affiliated with

Also associated with

Rating

Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of o will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2330319