Process for producing styrenic polymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526114, 526115, 526132, 526133, 526151, 526160, 526165, 526346, C08F 1208

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055960553

ABSTRACT:
There is disclosed a process for producing a styrenic polymer, especially, syndiotactic polystyrene, which comprises polymerizing a styrenic monomer by the use of a (a) transition metal compound, a (b) coordination complex compound comprising an anion in which a plurality of racicals are bonded to a metal and a cation or a Lewis acid, a (c) alkylating agent (alkyl group-containing aluminum, magnesium or zinc compound) and a (d) reaction product between a straight-chain alkylaluminum having at least two carbon atoms and water (alkylaluminoxane). The above process is capable of simplifying the production process and producing high-performance styrenic polymer having a high degree of syndiotactic configuration in high catalytic activity without deteriorating the catalyst activity, increasing the amounts of residual metals in the objective polymer or leaving the decomposition products of the alkylaluminum therein, thereby curtailing the production cost of the objective polymer.

REFERENCES:
patent: 5250629 (1993-10-01), Tani et al.
patent: 5329033 (1994-07-01), Spaleck et al.

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