Method for the preparation of alkyl tin halides

Details Method for the preparation of alkyl tin halides Method for the preparation of alkyl tin halides

1976-03-26

1977-08-23

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 722

Patent

active

040440354

ABSTRACT:
The preparation of alkyl tin halides is carried out by direct conversion of a gaseous lower aliphatic halide with a stannous halide in the presence of a nitrogenous solvent of the acid amide type at substantially atmospheric pressure. The acid amide solvent is present in quantities of approximately 1-4 mol per mol stannous halide. This reaction proceeds without the production of any trialkyl tin compounds as by-products.

REFERENCES:
patent: 3340283 (1967-09-01), Glaskey
patent: 3400141 (1968-09-01), Hoye et al.
patent: 3414595 (1968-12-01), Oakes
patent: 3475472 (1969-10-01), Suzuki et al.
patent: 3745183 (1973-07-01), Katsumura et al.
patent: 3824264 (1974-07-01), Bulten

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