Fluorinated glycidyl ethers and method of making

Details Fluorinated glycidyl ethers and method of making Fluorinated glycidyl ethers and method of making

1992-07-31

1993-07-13

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549215, 549516, C07D30128, C07D30322

Patent

active

052275027

ABSTRACT:
Novel fluorinated unsaturated glycidyl ethers are prepared by reacting 1,1,1-trifluoro-2-trifluoromethyl-3-buten-2-ol or 1,1,1-trifluoro-2-trifluoromethyl-4-propen-2-ol with chloromethyloxirane in the presence of onium salts. The fluorinated unsaturated glycidyl ethers are, in turn, subject to addition reaction with hydrosilanes in the presence of transition metal catalysts, obtaining novel silicon-modified glycidyl ethers or fluorinated organic silicon compounds.

REFERENCES:
patent: 3361685 (1968-01-01), Pittman et al.
patent: 3417035 (1968-12-01), Elmer et al.
patent: 3616462 (1971-10-01), Gurgiolo et al.

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