Preparation of alkali or alkaline earth metal cobalttetracarbony

Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing

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423417, 502174, 562406, C10G 104, B01J 2118, B01J 2720, C07C 5110

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045768099

ABSTRACT:
Alkali or alkaline earth metal cobalttetracarbonylates well suited for catalyzing carbonylation reactions, e.g., the carbonylation of organic compounds comprising halomethyl functions, are facilely prepared by reacting a cobalt (II) compound with carbon monoxide in the presence of (i) an inorganic base which comprises an alkali or alkaline earth metal hydroxide or an alkali or alkaline earth metal bicarbonate and (ii) at least one sulfur compound having at least one sulfur atom, the oxidation state of which being no greater than +3, and in a reaction medium comprising water, an alcohol, an ether, or admixture of water and an alcohol or an ether.

REFERENCES:
patent: 2865716 (1958-12-01), Hasek
patent: 3684491 (1972-08-01), Coffield et al.

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