Method of producing n-paraffin oximes

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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208143, 252472, 252473, B01J 110

Patent

active

039935540

ABSTRACT:
A process for converting mixtures of C.sub.6 to C.sub.30 n-paraffin and n-paraffin by-products to substantially pure n-paraffin which comprises catalytically hydrogenating the mixture at a temperature of from about 600.degree. to 750.degree. F. in the presence of a Group VIII metal on alumina catalyst where the catalyst contains from about 0.05 to 2.0 weight percent of an alkali metal oxide or alkaline earth metal oxide or thallous oxide. The catalyst can additionally contain a Group VIB or VIIB metal. The n-paraffin is photochemically reacted with a gaseous nitrosating agent to form paraffin oximes and by-products and the by-products are recycled for catalytic hydrogenation.

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patent: 3580837 (1971-05-01), Pollitzer
patent: 3775275 (1973-11-01), Rigdon et al.
patent: 3836453 (1974-09-01), Kovach et al.
patent: 3851001 (1974-11-01), Suggitt
patent: 3859370 (1975-01-01), Carter et al.

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