Process for the polymerization of alpha-olefins, catalyst employ

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429C, 526114, 526115, 526116, 526352, C08F 402, C08F 1002

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040370410

ABSTRACT:
Ethylene is polymerized through the use of an improved catalyst system consisting of a carrier such as neodymium oxide having a high superficial area, an aluminum compound such as triisobutylaluminum and the combination product of titanium trichloride and an isostructural chloride of another transition metal prepared by impregnating the carrier with a solution of a carbonyl derivative of the other transition metal, refluxing the impregnated carrier with titanium tetrachloride until that carbonyl derivative is converted to the chloride of the other transition metal, and then removing the excess of titanium tetrachloride.

REFERENCES:
patent: 2981725 (1961-04-01), Luft et al.
patent: 3008943 (1961-11-01), Guyer
patent: 3463827 (1969-08-01), Banks
patent: 3598795 (1971-08-01), Van den Berg
patent: 3745154 (1973-07-01), Kashiwa

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