Liquid clathrate aluminoxane compositions as co-catalysts with t

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502122, 502124, 502125, 502126, 502128, 502129, 502132, B01J 3100, B01J 3700, C08F 402, C08F 460

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059226315

ABSTRACT:
Olefin polymerization catalysts are described that comprise the reaction product of (a) a metallocene and/or a Ziegler-Natta catalyst compound (TICl.sub.4, etc.,) and (b) a liquid clathrate composition formed from (i) an aluminoxane, (ii) an organic, inorganic or organometallic compound, and (iii) an aromatic solvent. These liquid clathrates are obtained by the reaction, in aromatic solvents, of aluminoxanes such as, methylaluminoxane, with organic, inorganic or organometallic compounds that form stable clathrates with the aluminoxane and the solvent.

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