Photosensitive cell for the decomposition of water

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – With means applying electromagnetic wave energy or...

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204129, 423648R, 429111, C01B 306, C25B 104, B01J 1908

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active

045955689

ABSTRACT:
The invention relates to a photosensitive cell for the decomposition of water of the type formed by an aqueous medium containing a photosensitizer positively charged both in the reduced state and in the oxidized state, an acceptor, an oxygen forming catalyst and a hydrogen forming catalyst.
The cell according to the invention is characterized in that each of the two catalysts is fixed to a different support and in that the support of the oxygen forming catalyst is formed by a first, negative charge carrying colloid while the support of the hydrogen forming catalyst is formed by a second, positive charge carrying colloid.

REFERENCES:
patent: 3800159 (1974-03-01), Lucas
patent: 3924139 (1975-12-01), Hirose et al.
patent: 4011149 (1977-03-01), Nozik
patent: 4090933 (1978-05-01), Nozik
patent: 4367131 (1983-01-01), Gratzell et al.
Fisher, A. 1978, Splitting Water with Sunlight, Popular Science, vol. 212(6):66-68 and 183.
Journal of the American Chemical Society, vol. 103, No. 16, aout 12 1981 American Chemical Society, Gaston Pa. (US) D. Duonghong et al.: "Dynamics of Light-Induced Water Cleavage in Colloidal Systems", pp. 4685-4690.

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