Prevention of fouling in polymerization reactors and antistatic

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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44 63, 526 96, 526100, 526204, C08F 424, C08F 1000, C08F 214

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active

040680541

ABSTRACT:
An olefin is polymerized in a hydrocarbon diluent in a turbulent reaction zone to produce particles of polymer which are substantially insoluble in the diluent. Fouling of the reactor by adherence of polymer particles to the walls of the reactor is reduced by adding to the reaction medium a composition which comprises a porphyrin compound, alone or together with a metal alkyl sulfosuccinate. This composition is also useful as an antistatic agent for liquid hydrocarbons and halohydrocarbons.

REFERENCES:
patent: 3293075 (1966-12-01), Wildi
patent: 3669946 (1972-06-01), Koyanagi et al.
patent: 3962196 (1976-06-01), Weimer et al.
patent: 3995097 (1976-11-01), Brown et al.

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