Process for forming a cured article of consistent shape from an

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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523212, 264178R, 264183, 264236, 264247, C08K 906

Patent

active

054017815

ABSTRACT:
A process for forming a cured article of consistent shape from a hydrolyzable siloxane composition without the problem of non-uniformity that results from significant die swell upon extrusion and from shrinkage upon curing. The present process comprises extruding a non-self-supporting composition maintained at a temperature greater than 5.degree. C. The composition comprises a polydiorganosiloxane having at least two silicon-bonded hydrolyzable groups per molecule, a hydrolyzable silicon crosslinker, a filler, and optionally a curing catalyst. The composition is extruded at a constant rate through a shaping die to form a shaped extrusion having a cross-sectional area that is substantially uniform throughout the length of the shaped extrusion. The shaped extrusion is fed in a continuous flow into an aqueous curing bath which is maintained at a temperature of at least 20.degree. C. and which has a density substantially the same as or slightly greater than the density of the shaped extrusion. The shaped extrusion is moved through the aqueous curing bath at a constant rate as the shaped extrusion cures into a cured article having a cross-sectional area that is substantially uniform throughout the length of the cured article.

REFERENCES:
patent: 3184427 (1965-05-01), Russell et al.
patent: 3849462 (1974-11-01), Lengnick
patent: 4075154 (1978-02-01), Itoh et al.
patent: 4683251 (1987-07-01), Mikami
patent: 4783289 (1988-11-01), Shimizu et al.
EP 409079 Abstract only, publication date: Jan. 23, 1991.
The Handbook of Silicone Rubber Fabrication, W. Lunch, van Nostrand Reinhold Co. New York, N.Y. (1978).
Fabricating with Silastic.RTM. brand rubber, Bulletin 17-053a of Dow Corning Corporation (9-73).

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