Process for manufacturing polyester copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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528272, 528274, 528275, 528298, 528302, 528307, 528308, 5283086, 525437, C08F 2000, C08G 6302

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058958070

ABSTRACT:
A process for making a random polyalkylene terephthalate
aphthalate copolymer by synthesizing a bis-(hydroxyalkyl)-naphthalate composition under transesterification conditions, and subsequently combining the bis-(hydroxyalkyl)-naphthalate, a terephthalic acid, and an alkylene glycol under direct esterification conditions to form a random polyaklylene terephthalate
aphthalate copolymer. The preferred bis-(hydroxyalkyl)-naphthalate is bis-(2-hydroxyalkyl)-2,6-naphthalate, with bis-(2-hydroxyethyl)-2,6-naphthalate being the most preferred. Preferably, the bis-(hydroxyalkyl)-naphthalate is added at the initial stage of an acid-based polymer process, and polymerization is initiated or continued to produce a polyester copolymer. Alternatively, the bis-(hydroxyalkyl)-naphthalate is added to phthalate-based oligomers after the initial direct esterification stage, and polymerization is continued to produce a polyester copolymer.

REFERENCES:
patent: 4020049 (1977-04-01), Rinehart
patent: 5331082 (1994-07-01), Mossman et al.
patent: 5594092 (1997-01-01), Burkett et al.

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