Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1979-09-13
1980-12-23
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C17906
Patent
active
042412226
ABSTRACT:
An aliphatic or cycloaliphatic hydroperoxide or aliphatic dihydroperoxide, an olefin such as alpha-methylstyrene or a substituted alpha-methylstyrene wherein the substituent is on the phenyl ring and a t-cumyl halide corresponding to the hydrohalogenated olefin such as t-cumyl chloride or a substituted t-cumyl chloride are reacted under relatively non-aqueous conditions, in the absence of a free acid and in the presence of a phenol catalyst, to obtain a cumyl (or substituted cumyl) peroxide or diperoxide corresponding to the hydroperoxide or dihydroperoxide. The cumyl peroxides prepared by this reaction are very useful as crosslinking agents for polyethylene and elastomers.
REFERENCES:
patent: 3267066 (1966-08-01), Tijssen
patent: 3829503 (1974-08-01), Kato et al.
patent: 4133835 (1979-01-01), Bafford et al.
Chem. Abs. vol. 82, (1975), p. 125098n.
Lone Werren B.
Pennwalt Corporation
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