Purification of aluminum chloride

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium

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423138, C01F 762, C01G 4910

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active

043538827

ABSTRACT:
A method for the recovery of anhydrous aluminium chloride from a mixture of the aluminium chloride with ferrous chloride or ferric chloride, or both, which comprises subjecting the liquid mixture to a reduction in pressure, the conditions being such as to bring about dissociation of compounds of aluminium chloride and ferrous chloride present in the mixture, thereby to form an aluminium chloride-rich vapour and an iron chloride-rich solid and then separately collecting of the iron-and aluminium-rich components under conditions which give the minimum opportunity for recombination.

REFERENCES:
patent: 2387228 (1945-10-01), Arnold
patent: 2816814 (1957-12-01), Plucknett
patent: 3938969 (1976-01-01), Sebenik et al.
S. Danov et al., Purification of Industrial Aluminum Chloride by Rectification on a Pilot Rectifying Column, USSR Trudy Po Nhimii I Khimicheskoi Tekhhologii, 1961, 4:727-430.

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