Preparation of aromatic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5116

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active

061145742

ABSTRACT:
A process for converting alkyl-substituted aromatic hydrocarbons, such as p-xylene or 2,6-dimethyl naphthalene to their corresponding dicarboxylic acids is disclosed, said process comprising contacting the alkyl-substituted aromatic hydrocarbon with a gaseous mixture containing oxygen, NOx, where x is 1 or 2, and an inert gas, and heating the resulting mixture at a temperature from 90 .degree. C. to 250 .degree. C. and at a pressure of from 300 psi to 2500 psi for a period of time sufficient to convert the alkyl substitutents on the aromatic hydrocarbons to carboxyl groups.

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Panov, et al, Applied Catalysis A: General, vol. 82, pp. 31-36 (1992).

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